Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker.

نویسندگان

  • Daniel J Clingerman
  • William Morris
  • Joseph E Mondloch
  • Robert D Kennedy
  • Amy A Sarjeant
  • Charlotte Stern
  • Joseph T Hupp
  • Omar K Farha
  • Chad A Mirkin
چکیده

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).

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عنوان ژورنال:
  • Chemical communications

دوره 51 30  شماره 

صفحات  -

تاریخ انتشار 2015